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A step-by-step guide with formulas for all 15 categories, emission factors, GWP conversion and quality checks — with a free Excel calculator and PDF
11 steps · worked example included · Start the guide
Alcance 3 emissions are the indirect greenhouse gas emissions in your value chain — from the materials you buy to the use and disposal of what you sell. For most companies they are the largest part of the footprint, and you can calculate them in Excel with one equation applied consistently.
This guide walks through the full method, step by step: the core formula, the 15 categories, the four calculation methods, emission factors, unit conversion, CO₂e conversion, the Excel model, quality checks and reporting. Every formula is shown, and a worked example runs from raw data to a final total.
Toda la Alcance 3 calculation follows the same structure: an amount of activity multiplied by an emission factor for that activity.
Applied to each activity i and summed, it gives your total Scope 3 emissions:
When your emission factors are given per gas rather than in CO₂e, calculate each gas separately and convert with its global warming potential (Step 8):
El GEI Protocol Corporate Value Chain (Alcance 3) Standard divides value-chain emissions into 15 categories. Start by screening all 15 to find the ones that matter most for your company, then focus data collection there.
| Aguas arriba | Aguas abajo |
|---|---|
| 1. Bienes y servicios adquiridos | 9. Transporte y distribución aguas abajo |
| 2. Bienes de capital | 10. Procesamiento de productos vendidos |
| 3. Actividades relacionadas con combustibles y energía | 11. Uso de productos vendidos |
| 4. Transporte y distribución aguas arriba | 12. Tratamiento al final de la vida útil de productos vendidos |
| 5. Residuos generados en las operaciones | 13. Activos arrendados aguas abajo |
| 6. Viajes de negocios | 14. Franquicias |
| 7. Desplazamientos de empleados | 15. Inversiones |
| 8. Activos arrendados aguas arriba |
Report every relevant category, and document the reason for any category you exclude. The inventory should cover all seven Kyoto gases: CO₂, CH₄, N₂O, HFCs, PFCs, SF₆ and NF₃.
Four methods are used in practice. They share the same equation; what differs is the quality of the data behind each factor.
| Método | Fórmula | When to use |
|---|---|---|
| Supplier-specific | E = Σ Qj × EFsupplier,j | Suppliers provide product-level emissions data |
| Híbrido | E = Σ ADi × EFi, mixing supplier and secondary data | The usual approach for material categories |
| Average-data | E = Σ ADi × EFaverage,i | Physical quantities are known, supplier data is not |
| Spend-based | E = Σ Spendi × EFEEIO,i | Screening, or when only spend data exists |
Spend-based factors come from environmentally extended input–output (EEIO) models and are expressed per unit of currency (kg CO₂e per USD, for example). Use them for screening and fill gaps with physical data as it becomes available.
Activity data is the backbone of the inventory. Record one row per activity, with the quantity, its unit and the emission factor it links to.
| Categoría | Activity | Quantity | Unidad | Region | EF_ID |
|---|---|---|---|---|---|
| 1 Purchased goods | Steel procurement | 10,000 | kg | Global | EF_STEEL_01 |
| 1 Purchased goods | Plastic procurement | 2,500 | kg | Global | EF_PLASTIC_01 |
| 4 Upstream transport | Road freight | 20,000 | tonne-km | EU | EF_TRUCK_EU |
| 6 Business travel | Long-haul air travel | 15,000 | passenger-km | Global | EF_AIR_LONG |
| 7 Employee commuting | Car commuting | 120,000 | passenger-km | Japón | EF_CAR_JP |
| 5 Waste | Landfill waste | 350 | tonne | Japón | EF_LANDFILL_JP |
| 3 Fuel upstream | Natural gas upstream | 50,000 | kWh | Japón | EF_NG_UPSTREAM |
| 11 Use of sold products | Appliance electricity use | 400,000 | kWh | US | EF_GRID_US |
Typical sources are purchase orders and invoices, ERP exports, carrier reports, travel booking data, employee surveys, waste manifests and supplier questionnaires. Record the source and a data quality rating (primary, secondary or estimated) for every row.
Match each activity to an emission factor with the same unit, geography and system boundary. Follow this order for every row:
A key boundary rule: life cycle factors for fuels already include combustion. For Category 3, use only the upstream part, or you will double-count Scope 1:
Common factor sources include government sets (UK DESNZ conversion factors, US EPA Emission Factors Hub, Japan’s national factors), international bodies (IPCC, IEA, ICAO, IMO, the GLEC Framework for freight), life cycle databases (ecoinvent, LCA para expertos (GaBi), IDEA for Japan) and EEIO models (USEEIO, EXIOBASE).
The activity unit must match the factor’s denominator. Convert before multiplying.
| Desde | To | Conversión |
|---|---|---|
| kg | tonne | tonne = kg × 0.001 |
| tonne and km | tonne-km | tonne-km = tonne × km |
| MWh | kWh | kWh = MWh × 1,000 |
| one-way km | round-trip km | round trip = one-way × 2 |
Freight is the most common conversion. A 25-tonne shipment over 800 km is:
Each category applies the core equation to its own activity data. Use this formula library:
| Categoría | Fórmula |
|---|---|
| 1 Purchased goods and services | E = Σ Massi × EFmaterial,i or Σ Spendi × EFsector,i |
| 2 Capital goods | E = Σ Quantityi × EFproduct,i |
| 3 Fuel- and energy-related | E = Σ Fuelf × EFupstream,f + Electricity × EFciclo de vida × Loss rate |
| 4 Upstream transportation | E = Σ Massi × Distancei × EFtransport,i or Σ Fuelf × EFf |
| 5 Waste in operations | E = Σ Wastei × EFtreatment,i |
| 6 Business travel | E = Σ Distancei × EFmodo,i + Nights × EFhotel |
| 7 Employee commuting | Distanceanual = Employees × One-way km × 2 × Working days; E = Σ Distancemode × EFmode |
| 8 Upstream leased assets | E = Σ Fuelf × EFf + Electricity × EFred |
| 9 Downstream transportation | E = Σ Massi × Distancei × EFtransport,i |
| 10 Processing of sold products | E = Σ Fuelf × EFf + Σ Process emissionp × GWPp |
| 11 Use of sold products | E = Units sold × Annual energy × Lifetime × EFenergía |
| 12 End-of-life treatment | E = Σm Σt Massm × Sharet × EFm,t |
| 13 Downstream leased assets | E = Fuel × EFcombustible + Electricity × EFred |
| 14 Franchises | E = Σ (EScope 1,i + EScope 2,i) |
| 15 Investments | E = Σ (EScope 1+2, investee × Share of investment) |
When you have emissions per gas, multiply each by its 100-year global warming potential (GWP) and add them up:
| Gas | GWP100 (IPCC AR6) |
|---|---|
| CO₂ | 1 |
| CH₄ (fossil) | 29.8 |
| CH₄ (non-fossil) | 27.0 |
| N₂O | 273 |
| HFC-134a | 1,530 |
| HFC-23 | 14,600 |
| CF₄ (PFC-14) | 7,380 |
| SF₆ | 25,200 |
| NF₃ | 17,400 |
Example: 10 kg of fossil methane is 10 × 29.8 = 298 kg CO₂e. Use one GWP set consistently across the whole inventory, and state which one you used.
A clean model separates inputs, factors and calculations, so every number can be traced. The free DEISO calculator uses this structure:
The key formula looks up the factor for each row and multiplies it by the quantity. In Excel 365:
For compatibility with every Excel version, the calculator uses INDEX and MATCH:
When a factor is given per gas instead of in CO₂e, the calculator switches automatically to the gas route: CO₂ + CH₄ × GWP + N₂O × GWP.
Before you report, check the inventory for the errors that most often distort Alcance 3 results:
| Check | What it catches |
|---|---|
| Missing EF_ID | Activities with no factor assigned |
| Factor not found | An EF_ID that does not exist in the library |
| Unit mismatch | Activity units that differ from the factor unit |
| Zero result | A quantity above zero that produced zero emissions |
| Duplicate Record_ID | The same activity counted twice |
| Missing geography | Rows where the factor region cannot be checked |
In Excel, a missing-factor check is as simple as =COUNTIF(Activity_Data!K:K,"") for the rows you have filled. All checks should pass before the numbers leave the workbook.
Sum the row results by category, and report each category’s share of the total. The example data from Step 4 gives:
| Categoría | Activity | Calculation | Emissions (kg CO₂e) |
|---|---|---|---|
| 1 | Steel procurement | 10,000 × 1.90 | 19,000 |
| 1 | Plastic procurement | 2,500 × 2.70 | 6,750 |
| 3 | Natural gas upstream | 50,000 × 0.02 | 1,000 |
| 4 | Road freight | 20,000 × 0.10 | 2,000 |
| 5 | Landfill waste | 350 × 450 | 157,500 |
| 6 | Long-haul air travel | 15,000 × 0.15 | 2,250 |
| 7 | Car commuting | 120,000 × 0.19 | 22,800 |
| 11 | Appliance electricity use | 400,000 × 0.38 | 152,000 |
| Total de Alcance 3 | 363,300 (363.3 t CO₂e) |
The emission factors in this example are training values chosen to show the method. Replace them with factors from a recognised source before you report any result.
Alcance 3 emissions are calculated as activity data multiplied by an emission factor, E = AD × EF, for each activity, and then summed across all activities and categories.
El GEI Protocol Corporate Value Chain (Alcance 3) Standard defines 15 categories: 8 upstream and 7 downstream.
Debe informar de todas las categorías pertinentes y documentar el motivo de excluir cualquier categoría que no sea pertinente o significativa.
Utilice métodos específicos de proveedores o híbridos para las categorías más relevantes, métodos basados en datos promedio cuando conozca las cantidades físicas y métodos basados en el gasto para una evaluación preliminar o cuando solo disponga de datos de gasto.
Yes. A well-structured Excel model with an activity data sheet, an emission factor library, a calculation sheet and quality checks is enough for a complete, auditable Alcance 3 inventory.
Use one set consistently. Current practice is the 100-year global warming potentials from the IPCC Sixth Assessment Report (AR6), for example 29.8 for fossil methane and 273 for nitrous oxide.
DEISO desarrolla GEI Protocol and ISO 14064-1 inventories, including Alcance 3 screening across all 15 categories and Scope 3-only inventories.
Go beyond the template. The DEISO Scope 3 emissions and product carbon footprint (PCF) training teaches practical value-chain accounting and PCF análisis del marco del GEI Protocol framework — instructor-led, for sustainability professionals, engineers and consultants, starting when you are ready.
Prefer to try it first? Download the free calculator and PDF guide.
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